Palladium(II)-Catalysed Oxidation of Alkenes
نویسندگان
چکیده
منابع مشابه
Platinum-catalysed aerobic 1,2-aminooxygenation of alkenes.
Platinum(II) salts in combination with copper salts and molecular oxygen catalyse an unprecedented intramolecular transfer of heteroatoms to alkenes to yield aminooxygenation products under sustainable conditions.
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Substoichiometric loadings of DBU catalyse the efficient 1,4-addition of alcohols and non-nucleophilic amines such as pyrrole to activated alkenes; the application of this methodology in a one-pot synthesis of a natural product, and as a novel strategy for the synthesis of mono-protected 1,3-carbonyl compounds is reported.
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A non-heme iron complex catalyses the oxidation of allylic, benzylic, and aliphatic C-H bonds by O(2). During this reactivity, a ferric hydroperoxide species is observed. The kinetic analysis of this complex's formation may suggest a ferric superoxo species as the initial metal-based oxidant.
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Isoniazid (isonicotinic acid hydrazide) is stable in the solid state and in concentrated aqueous solutions. In dilute aqueous solutions, however, it breaks down under certain conditions. This breakdown has been shown to require oxygen (and hence may be described as an auto-oxidation) and certain metal ions, either free, such as Mn2+, Cu2+, Fe"+, or combined as haemin; and to be accelerated by i...
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ژورنال
عنوان ژورنال: Synthesis
سال: 2015
ISSN: 0039-7881,1437-210X
DOI: 10.1055/s-0035-1560465